Molecular Origin of Strain-Induced Chain Alignment in Pdpp-Based Semiconducting Polymers
- Type: Conference Presentation
- Conference Type: AIChE Annual Meeting
- Presentation Date: November 15, 2021
- Duration: 15 minutes
- Skill Level: Intermediate
- PDHs: 0.50
Herein, we performed a detailed study on the chain deformation mechanism for a series of side-chain engineered diketopyrrolopyrrole (DPP)-based semi-flexible D-A polymers. We started with thin-film tensile tests and CG-MD simulations to explore the fundamental mechanism of the macroscopic deformation process. Next, wide/small-angle hard X-ray scattering, wide-angle tender X-ray scattering, polarized UV-vis spectroscopy, NEXAFS, and atomic force microscopy (AFM) were applied to investigate the microstructural chain alignment upon thin-film deformation, which was further confirmed by the CG-MD simulations. Later, organic field-effect transistors (OFETs) were fabricated to test the effect of strain-induced chain alignment on device performance.
The detailed morphological analysis demonstrates (1) highly aligned polymer crystallites upon deformation, while the degree of backbone alignment is limited within the crystalline domain. (2) Besides, the aromatic ring on polymer backbones rotates parallel to the strain direction despite the relatively low overall chain anisotropy. (3) The effect of side-chain length on the DPP chain alignment is observed to be less noticeable when compared with its drastic influence on stress-strain responses. These observations are distinct from traditional linear-chain semicrystalline polymers like polyethylene due to distinct characteristics of backbone/side-chain combination and the crystallographic characteristics in DPP polymers. Furthermore, a stable and isotropic charge carrier mobility is obtained from fabricated organic field-effect transistors. This study deconvolutes the alignment of different components within the thin-film microstructure and highlights that crystallite rotation and chain slippage are the primary deformation mechanisms for semiconducting polymers.
|AIChE Member Credits||0.5|
|AIChE Graduate Student Members||Free|
|AIChE Undergraduate Student Members||Free|