(106f) H2SO4 Catalysis: Perspective and Opportunities for Reducing SO2 Emissions Using Particulate and Monolith Catalysts | AIChE

(106f) H2SO4 Catalysis: Perspective and Opportunities for Reducing SO2 Emissions Using Particulate and Monolith Catalysts

Authors 

Nagaraj, A. - Presenter, Texas A&M University-Kingsville
Mills, P., Texas A&M University-Kingsville



Novel Jet-loop Reactor for Kinetic Measurements of Gas-Solid Heterogeneous Catalyzed Reactions Involving Commercial-Scale Particles

H2SO4 Catalysis: Perspective and Opportunities for Reducing SO2 Emissions
Using Particulate and Monolith Catalysts
Anuradha Nagaraj
Department of Environmental Engineering
Texas A&M University-Kingsville
Patrick L. Mills
Department of Chemical and Natural Gas Engineering
Texas A&M University-Kingsville
Introduction. Development of next-generation chemical processes that have zero emissions is a key environmental objective for sustainable development. The manufacture of H2SO4 by the air oxidation of SO2 to SO3 is an important technology where an opportunity exists for new catalyst development and process innovation by reducing emissions of unconverted SO2 in process reactor tail gases owing to the sheer number (> 1500) and scale (ca. 500 to 4500 metric tons/day) of typical plants. The global supply of H2SO4 is projected to grow from 200 MM tonnes in 2006 to more than 258 MM tonnes in 2015 with a value of > $10 MMM [1]. An opportunity exists to develop new innovations in environmental catalysis and reaction engineering for an important technology that has a rich and long history with sustained economic growth. Best Available Control Technologies (BACT) for controlling SO2 emissions from stack gases involves additional processing resulting are cost intensive and well-studied. However, emissions control technologies using front-of-pipe technology, such as new catalyst technology, improved reactor designs, and process operational strategies have greater potential to be more economical versus end-of-pipe scrubbing technologies.
From a catalyst design perspective, specification of catalyst composition, catalyst size, catalyst shape and internal pore structure are interlinked parameters that have received notable attention by catalyst scientists and engineers since these properties affect the catalyst effectiveness factor, bed pressure drop, rate of catalyst attrition, catalyst mechanical integrity, catalyst life, amongst other key measures of performance. It is evident that specification of preferred catalyst design parameters requires careful optimization since tradeoffs exist in how the observed reaction rate and other measures of performance may be affected by altering one or both of these parameters.
The primary objective of this study is three-fold: (1) to review the current H2SO4 catalysts utilized in the oxidation of SO2 to SO3; (2) to evaluate monolith catalysts as potential candidates as SO2 oxidation
catalysts; and (3) to develop modeling framework to compare reactor designs for both particulate and monolith catalysts under typical multi-pass convertor operation that can be used as the starting basis for process optimization.
Methods. Typical commercial H2SO4 catalyst compositions consist of silica support, vanadium and possibly metal promoters. The current state-of-the-art of both particulate and monolithic catalysts based upon recent open and patent literature will be reviewed.
COMSOL Multiphysics is used to model non-isothermal diffusion, reaction and transport effects in both various particulate and monolith catalyst geometries with compositional and temperature dependence of all model parameters. This builds upon our previous work [2] on modeling of transport- kinetic interactions in SO2 oxidation commercial catalysts shapes, such as solid and hollow cylinders and various types of multi-lobe catalyst shapes. There is a knowledge gap in monolith modeling for SO2 oxidation to SO3 since the only open literature on modeling on monoliths was the numerical model developed by Bespalov et al. in 1991 [3]. Therefore, it is important to develop advanced models for better understanding of the transport-kinetic interactions that occur between the monolith channel and monolith microstructures that can be created by various catalyst synthesis protocols.
In this work, a new model is described that accounts transport-kinetic interactions for SO2 oxidation in monolith catalysts that is valid for process conditions encountered in typical commercial-scale multi- pass convertor operation. The reaction kinetic model is based upon the work of Collina et al. [4] since it accounts for the dependence of the SO2 oxidation rate on the partial pressures of SO2, O2, and SO3 with inhibition by both SO2 and SO3. The reaction rate and adsorption equilibrium parameters in this model
are valid from 420 to 550oC, which is within the commercial operating range of most convertors.
COMSOL Reaction Engineering Lab is used to study various adiabatic reactor designs for SO2 converter performance under ideal plug flow conditions, while a more advanced COMSOL Multiphysics model is described that accounts for non-ideal gas and thermal energy interphase and intraphase transport effects.
Results and Discussion. Typical adiabatic 4-pass converter profiles are shown in Figure 1. These are based upon COMSOL Reaction Engineering Lab to describe adiabatic reactor performance with ideal plug flow of the gas. These results provide the incentive for developing new catalyst technology because the maximum SO2 conversion possible is 99.7%, which is adequate to meet current EPA regulations for SO2 emissions. However, it does not meet the anticipated future need to design H2SO4 plants with SO2 emissions < 100 ppm, or even < 10 ppm.
Additional results that compare the performance of particulate versus monolithic catalyst shapes using typical process conditions will be presented and discussed, thereby showing the incentive for development of monolithic catalyst with higher activity and reduced emissions.

Figure 1. Adiabatic 4-pass converter profiles

References

1. British Sulphur Consultants, Sulphuric Acid : Global Supply and Demand in the Next Decade, Topsøe Catalysis

Forum â?? Denmark, August 23rd to 24th 2007.

2. Nagaraj, A., & Mills, P. L. â??Analysis of Heat, Mass Transport, and Momentum Transport Effects in Complex Catalyst Shapes for Gas-phase Heterogeneous Reactions Using COMSOL Multiphysicsâ?. Paper Presented at the COMSOL Conference 2008 Boston, MA

3. Collina, A., Corbetta. D. and Cappelli, A. "Use of Computers in the Design of Chemical Plants," 97th Event of the European Federation of Chemical Engineering, Firenze (1970).

4. Bespalov, A.V., et al., â??Numerical modeling of sulfur dioxide oxidation reaction in through-channel of a block catalyst with a honeycomb structureâ?. Zhurnal Prikladnoi Khimii, 1991. 64(10): 2048-2053.

Topics 

Checkout

This paper has an Extended Abstract file available; you must purchase the conference proceedings to access it.

Checkout

Do you already own this?

Pricing

Individuals

AIChE Pro Members $150.00
AIChE Graduate Student Members Free
AIChE Undergraduate Student Members Free
AIChE Explorer Members $225.00
Non-Members $225.00