(4t) Explorations of Synthesis and Application of Mesoporous Nanoparticles

Authors: 
Chung, P. W., University of California, Berkeley



Explorations of Synthesis and Application of Mesoporous Nanoparticles

Po-Wen Chung, Ph. D

Department of Chemistry, Iowa State Uniersity, Ames, IA 50010

Department of Chemical and Biomolecular Engineering,

University of California, Berkeley, CA 94720

In light of the development of MCM-41 mesoporous silica materials, a variety of mesoporous nanoparticles have been synthesized by either using soft-template as structure directing agents or hard-template nanocasting replication.  Such mesoporous nanoparticles as mesoporous silica, mesoporous metal oxides, mesoporous organic-inorganic hybrid, mesoporous carbon and mesoporous polymer nanoparticles have drawn attention to their applications on drug delivery, catalysis, adsorption, separation, and energy storage.  Herein, my doctoral research has demonstrated the novel synthesis of mesoporous organic-inorganic hybrid silica nanoparticles, highly ordered mesoporous carbon nanoparticles, and mesoporous metal oxides as well as the applications of drug delivery, separation and catalytic supports for sustainable chemistry by using aforementioned nanoparticles.  Furthermore, my postdoctoral research has unveiled the unprecedented adsorption of glucans on mesoporous carbon materials, and is currently in pursuit of exploring efficient routes of depolymerizing lignocellulosic biomass.

Selected Publications:

1.)            Po-Wen Chung,* Alexandre Charmot, Oz M. Gazit, and Alexander Katz,* “Glucan Adsorption on Mesoporous Carbon Nanoparticles: Effect of Chain Length and Internal Surface”, Langmuir 2012, 28, 15222-15232. (ISI impact factor: 4.186)

2.)            Po-Wen Chung,* Tae-Wan Kim, Yulin Huang, Weihua Deng, Brian G. Trewyn, Robert C. Brown and Victor S.-Y. Lin “Ordered Mesoporous Carbon Nanoparticles as a Catalyst Support for Syngas Reaction”, manuscript in submission.

3.)            Po-Wen Chung, Rajeev Kumar, Marek Pruski and Victor S.-Y. Lin,* “Temperature Responsive Solution Partition of Organic-Inorganic Hybrid Poly(N-isopropylacrylamide)-coated Mesoporous Silica Nanoparticles”,  Advanced Functional Materials, 2008, 18(9), 1390-1398. (ISI impact factor: 6.990)

4.)            Tae-Wan Kim,* Po-Wen Chung and Victor S.-Y. Lin, “Facile Synthesis of MCM-48 Ordered Mesoporous Silica Nanoparticles with Control of the Particle Size”, Chemistry of Materials, 2010, 22, 5093-5104. (ISI impact factor: 5.368)

5.)            Tae-Wan Kim, Po-Wen Chung, Igor I. Slowing, Makoto Tsunoda, Edward S. Yeung, and Victor S.-Y. Lin,* “Structurally Ordered Mesoporous Carbon Nanoparticles as Transmembrane Delivery Vehicle in Human Cancer Cells”,  Nano Letters, 2008, 8(11), 3724-3727. (ISI impact factor: 9.991)

6.)            Tae-Wan Kim,* Igor I. Slowing, Po-Wen Chung, and Victor S.-Y. Lin, “Ordered Mesoporous Polymer-Silica Hybrid Nanoparticles as Vehicles for Intracellular Controlled Release of Macromolecules”, ACS Nano 2010, 5(1), 360-366. (ISI impact factor: 7.493)