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Process Safety Technical Areas

Methods for Precluding the Existence of a Dust-Explosion Hazard

Mar 14, 2011
Richard Prugh
The "generic" standard for preventing fires and explosions involving combustible dusts is the National Fire Protection Association publication NFPA 654. In this document, fifteen of the requirements are prefaced with the phrase "if an explosion hazard exists", and an additional four requirements...

Making Existing Process Plants Inherently Safer

Mar 14, 2011
Victor H. Edwards
Making process plants inherently safer has obvious advantages and is easiest to do when designing a new plant. Modification of existing plants to make them inherently safer can often be much more difficult and costly, including any costs due to lost production. However, an inherently safer design...

Secondary Dust Explosions: How to Prevent Them or Mitigate Their Effects?

Mar 14, 2011
Jérôme R. Taveau
Dust explosions are frequent and particularly devastating in the process industries, and secondary dust explosions are the most severe ones. A secondary dust explosion can occur when the blast wave from a primary explosion entrains dust layers present in the plant, creating a large dust-air...

Analysis of Independent Protection Layers Used In Three Typical Chemical Processes

Mar 14, 2011
Herb W. H. Meyer
Independent protection layers (IPLs) used to mitigate most severe consequences are analyzed for three chemical processes: Olefins, Low-density Polyethylene, and an intermediates chemical plant. The IPLs are categorized by type (i.e., interlocks, PSVs, independent alarms, etc.), by function (...

Effect of Physical Properties of Particulates on Fires and Dust Explosions

Mar 14, 2011
Konanur Manjunath
There has been a dramatic approach in the way we are implementing process safety guidelines and standards for combustible. This is particularly true for North America where there have been devastating dust explosions occurring for the last 10 years or so. Following this, OSHA has initiated NEP,...

The UK Experience In Managing Risks Arising From Human Error

Mar 13, 2011
David Embrey
Following the Piper Alpha incident in the North Sea, both offshore and onshore Oil and Gas operators in the UK were required under the COMAH (Control of Major Accident Hazards) regulations to submit a Safety Case setting out how the risks in their installations were to be managed. After many years...

Improvement of BLEVE Overpressure Method Using Historical Data

Mar 13, 2011
Fei Chen
The current CCPS/TNO's BLEVE (Boiling Liquid Expanding Vapor Explosion) overpressure methodology is derived from that published by Baker in 1975. This methodology assumes isentropic expansion work and uses Baker's graphical method and high-explosive correlation to calculate BLVE energy and...

Safety Studies for Reformatsky Chemistry In a Meso-Scale Continuous Process System

Mar 13, 2011
Gabriel Loh
The production of fine chemicals and pharmaceuticals has been traditionally achieved via batch processes. More recently, there has been interest in using multiscale (meso- and micro-) reactors for the production of these fine chemicals and pharmaceuticals. These efforts in process intensification...

Human Performance Training

Mar 13, 2011
Don D. Nguyen
Operator competency has been a major challenge for the petrochemical and refining industry for decades. In recent times, human factors are believed to be a consistent contributing cause for a lot of incidents. Current schemes used to determine an operator's competency are subjective and somewhat...

Kinetic Modeling of the Reactions Involved in the T2 Explosion

Mar 13, 2011
Ronald J. Willey
The runaway reaction at the chemical preparation facility called T2 laboratories in Jacksonville, Florida on December 19, 2007 is analyzed. The approached involved estimating kinetic parameters based on temperature time traces presented in the CSB final report for ARSST (Advance Reactive System...

Inherently Safer Reactor Design for Complex Reactions Based On Calorimetry Studies

Mar 13, 2011
Alba Lucia Pineda
A number of reactive processes of the agrochemical, fine-chemicals and pharmaceutical industries involve thermally unstable and/or toxic reactants, products or intermediates, for which the chemistry, thermochemistry and thermodynamic properties are barely known. They frequently employ multipurpose...

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