(127c) Modular Electrocatalytic Processing for Simultaneous Carbon Utilization and Alkane Conversion
Carbon Monoxide (CO) is an important industrial gas used in manufacturing bulk chemical precursors such as phosgene, commodity materials via carbonylation including aldehydes, ketones, carboxylic acids, anhydrides, esters, amides, imides, carbonates, ureas, and isocynanates. Further, high purity CO (>99.99%) is used in electronics manufacturing. Industrial bulk CO is produced by separating CO from syngas (containing H2) generated via steam methane reforming (SMR) using natural gas as the feedstock. The U.S. consumes approximately 300-400 MMscf/day of CO with an annual market value of nearly $2 billion.
Various separation technologies are used including cryogenic separation (i.e. cold box), pressure swing adsorption (PSA), membrane separation, and ammonium salt solution absorption. However, these processes are complex and capital intensive requiring larger production facilities. Although low temperature solution-based CO2 electrolyzers are being studied, solid oxide electrolyzer cells (SOECs) operating at an elevated temperature provide greater cell/electrolysis efficiencies. The ability to utilize solid oxide electrolyzer cell (SOEC) technology to electrochemically convert CO2 into CO/O2 or CO2/H2O into syngas/O2 has been shown over recent years [1-3].
Ohio University (OHIO) with funding from the U.S. Department of Energyâs National Energy Technology Laboratory (NETL) Carbon Use and Reuse Program (DE-FE0031709) is developing a process that utilizes solid oxide electrolysis to simultaneously convert CO2 and ethane contained in wet natural gas into valuable products. OHIOâs SOEC process seeks to advance beyond these previous electrochemical CO2 reduction concepts by utilizing intermediate-temperature operation (650-750Â°C) and utilizing an innovative cell design which incorporates oxidative dehydrogenation (ODH) of C2+ alkanes. Several transition metals and mixed metal oxides have been identified as suitable for solid oxide electrolysis of CO2 and ODH of C2+ alkanes using first principles simulations  and experimental trials, respectively. This presentation will discuss recent results from OHIOâs carbon utilization project including experimental results and process simulations.
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