(622a) A Systematic Methodology for the Modeling of Intrinsic Chemical Reaction Kinetics: NHexane Hydroisomerization On a Bifunctional Zeolite
 Conference: AIChE Annual Meeting
 Year: 2013
 Proceeding: 2013 AIChE Annual Meeting
 Group: Education Division
 Session:
 Time: Thursday, November 7, 2013  8:30am8:52am
Kinetic
modeling of chemical reactions is, among others, an important item of chemical
engineering education. The presented work focuses on a systematic methodology
for modeling the nonisothermal intrinsic kinetics of chemical reactions
allowing their later incorporation into more complex reactor models. While a
dedicated experimental campaign should typically aim at the acquisition of
intrinsic kinetics, transport phenomena at the industrial reactor scale can be
accounted for via wellknown correlations from literature [1].
The
proposed methodology start with an analysis of the experimental data as a
function of the operating conditions, see Figure 1. Insights in the actual
reaction mechanisms are pursued and first considerations with respect to the
structure of the corresponding rate equations can be made. As a second step in
the construction of a kinetic model, a preliminary determination of the kinetic
parameters is performed. This is necessary since the response surface
determined by the objective function, i.e., the sum of squares of residuals of
the responses, may contain multiple maxima and minima. This can be done via a
literature survey or quantum chemical calculations. An alternative method to
determine good initial parameter values for preexponential factors and
activation energies/reaction enthalpies, is to perform an isothermal regression
for each temperature and fit the results to the Arrhenius equation. Thirdly,
the actual nonisothermal regression is performed. Lastly, the regression
results are analyzed. This is based on a statistical analysis and verification
if the kinetic model and parameters obtained are physically viable. The
statistical analysis comprises the investigation of the confidence intervals,
binary correlation coefficients, test for model adequacy, regression and
parameter significance and residual analysis (performance plots, residual
figures, parity diagrams and QQ plots).
Figure 1: Proposed methodology for kinetic modeling
A
simple, yet challenging, reaction is taken as example through this
contribution, i.e., the hydroisomerization of nhexane on a bifunctional
catalyst MC389, i.e., a with platinum impregnated USY derived catalyst. The
metallic function of the catalyst allows to operate at milder conditions. This
is due to the dehydrogenation of the physisorbed alkanes which occurs on the Pt
sites and results in the formation of olefins, see Figure 2. It also provides
resistance against coking.
Figure 2:
Schematic overview of (ideal) hydroisomerization of nhexane over a
bifunctional zeolite
These
olefins are then relatively easily protonated on the acid sites, where the
actual conversion to isomers and cracked products occurs. Only 3 reaction
products are observed: 2methylpentane, 3methylpentane and propane. The
experimental conditions ranged from 493 to 573 K, 1.0 to 2.0 MPa and a molar
hydrogen to hydrocarbon ratio of 50 to 100 mol mol^{1} at a spacetime
of 191.0 kg_{cat} s mol_{C6}^{1}.
These reaction conditions resulted in socalled ideal hydrocracking [24].
Ideal hydrocracking occurs if the acid catalyzed conversion reactions are the
rate determining steps, which leads to very specific kinetic behavior. Figure 3
shows the experimental and simulated conversion of nhexane by
hydroisomerization on MC389 catalyst as function of temperature at different
hydrogen to nhexane molar feed ratios. With increasing hydrogen to nhexane
ratio, the conversion is decreasing which indicates that (de)hydrogenation is
in quasiequilibrium.
Figure 3: Conversion of nhexane by hydroisomerization
on MC389 catalyst as function of temperature at different hydrogen to nhexane
molar feed ratios. Lines are calculated by the kinetic model. Circles, full
line: F^{0}_{H2} / F^{0}_{C6} = 50 mol mol^{1};
squares, dashed line: F^{0}_{H2} / F^{0}_{C6} =
75 mol mol^{1}; triangles, dotted line: F^{0}_{H2} / F^{0}_{C6}
= 100 mol mol^{1}.
The
reaction network was constructed under the validated assumptions of ideal
hydrocracking kinetics and the corresponding rate equations were derived:
in
which p_{C6} is the partial pressure of nhexane, K_{phys} is the equilibrium coefficient for
physisorption, k_{i}^{comp} is
the composite rate coefficient for pcpbranching or
betascission. The rate coefficients and equilibrium coefficient are described
by a reparametrized Arrhenius or Van ?t Hoff equation in order to decrease the
binary correlation between the preexponential factor and activation energy:
In
total, 8 kinetic parameters are determined, i.e., the rate and equilibrium
coefficients at the mean temperature, i.e., k_{Tm} and K_{Tm}, and the corresponding activation
energy and reaction enthalpy. Good initial guesses were acquired via isothermal
regression, see Figure 4 and Table 1.
Figure 4: Arrhenius plots, ln(k)
and ln(K) as function of the reciprocal of
temperature for which an initial guesses for the preexponential factors and
activation energies/reaction enthalpy are obtained for nonisothermal
regression.
Table 1: Determined values of the kinetic/equilibrium
coefficient at average temperature and activation energy and reaction enthalpy
by the isothermal regression and the Arrhenius plots, see Figure 4.
k_{Tm}_{}or K_{Tm} (10^{6} mol s^{1} kg_{cat}^{1} or Pa^{1}) 
E_{a} or ΔH (kJ mol^{1}) 

k_{pcp}_{(1),comp } 
264.9 
68.0 
k_{pcp}_{(2),comp } 
116.5 
61.1 
k_{bs,comp}_{} 
16.5 
62.8 
K_{phys} 
1.2 10^{5} 
79.5 
Nonisothermal
regression, i.e., regression taking into account of all experimental data at
once, led to the significant determination of all 8 kinetic parameter, see
Table 1.
Table 2: Parameter estimates, corresponding
confidence interval and t values of the kinetic/equilibrium coefficients at
average temperature and activation energies and reaction enthalpy determined by
nonisothermal regression.
k_{Tm}_{}or K_{Tm} (10^{6} mol s^{1} kg_{cat}^{1} or Pa^{1}) 
E_{a} or ΔH (kJ mol^{1}) 

k_{4a,obs} 
258.6 ± 38.9 
65.5 ± 9.2 
k_{4b,obs} 
115.7 ± 17.8 
57.1 ± 8.8 
k_{5,obs} 
15.4 ± 5.8 
65.8 ± 24.2 
K_{1} 
(1.1 ± 0.9) 10^{5} 
83.4 ± 34.4 
The
model has a higher F value for the global significance of the
regression, i.e., 758.4, than the corresponding tabulated F value, i.e.,
3.9. All parameters are estimated significant as indicated by the relatively
narrow confidence intervals. The parameter estimates also have a clear physical
meaning. All binary correlation coefficient were lower than 0.95 which
indicates that all parameters are uncorrelated with each other. A residual
analysis showed that the model is capable of predicting the experimental
observations, as shown the performance figure (Figure 5). Also the residuals
seem to be normally distributed with an expected value equal to 0 and without
having any systematic deviations as function of the independent variables as
shown by the residual figure (Figure 6) and QQ plot (Figure 7).
Figure 5: Product yield of
nhexane hydroisomerization on MC389 catalyst as function conversion. Lines
calculated by the kinetic model. Circles, full line: 2methylpentane; squares,
dashed line: 3methylpentane; triangles, dotted line: propane.
Figure 6: Residual figure for the molar outlet flow
rate of 2methyl pentane temperature determined by the kinetic model.
Figure 7: QQ plot of the residuals of the molar
outlet flow rate of 2methyl pentane determined by the kinetic model.
In
summary, a systematic methodology for nonisothermal modeling of intrinsic
chemical kinetics has been proposed. Inspection of the experimental data leads
to an increased insight in the reaction mechanism and corresponding rate
equations. Good initial parameter values are essential to obtain the optimal
parameter values during non isothermal regression and can be acquired via
isothermal regression. After regression, statistical tools can be used to
evaluate the significance of the regression and performance of the model. This
methodology has been successfully applied to nhexane hydroisomerization
on a bifunctional zeolite.
[1]
G.F. Froment, K.B. Bischoff, Chemical reactor
analysis and design (1990)
[2] T.F. Degnan,
C.R. Kennedy, AIChE Journal. 39 (1993) 607614.
[3] G.E. Gianetto,
G.R. Perot, M.R. Guisnet, Ind. Eng. Chem. Res. 25 (1986) 481490.
[4] J.W. Thybaut, C.S.L. Narasimhan, J.F. Denayer, G.V. Baron, P.A. Jacobs, J.A.
Martens, G.B. Marin, Ind. Eng. Chem. Res. 44 (2005) 51595169.
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