(605f) Patterned Substrates to Direct Self-Assembly of Particle Monolayers

As current lithographic techniques approach practical engineering limits for resolution, directed self-assembly of nanoparticles becomes an attractive scalable nanomanufacturing process for creating  ordered arrays of particles at a variety of length scales that could be used both as patterning agents and functional materials.  However the roles of interparticle forces and external fields on directed  self-assembly of particles is not well understood.  In this presentation density functional theory (DFT) and molecular dynamics (MD) simulations are used to explore the use of larger scale patterned substrates to drive smaller scale directed self-assembly of particle monolayers.  Square patterned substrates with varying energy barriers at length scales N-fold  the final desired particle pitch are considered (N>1).  Ranges of N, bulk density and patterned substrate field strength are identified that disrupt the entropically favored hexagonally close-packed lattice and promote square lattice formation for hard-spheres.  Event-driven MD simulations are then employed to verify the predictions from DFT and to analyze the dynamics of the self-assembly process.  The effects of interparticle forces and other geometries of patterned substrates are considered.  These DFT and MD results are used to discuss and define the energetically and kinetically accessible spaces for non-hexagonal lattice formation.