(379c) Connectedness in Irreversibly Built Structures
AIChE Annual Meeting
2006
2006 Annual Meeting
Computational Molecular Science and Engineering Forum
Carol in Thermoland I: a Session in Honor of Carol Hall's 60th Birthday
Wednesday, November 15, 2006 - 1:25pm to 1:50pm
Simulations and integral-equation theory were applied to the problem of connectedness on a layer of sequentially quenched particles. The deposition algorithm is a particular limit of an irreversible adsorption in which slowly added particles are allowed to equilibrate one at a time. The theory for this essentially polydisperse system was simplified by treating it as a quenched-annealed quasi-binary mixture. An approximation to a three-body connectedness function is needed, in addition to a closure for the Ornstein-Zernike equation.