Pilot Plant NO2 Removal with Aqueous Sulfite
Carbon Management Technology Conference
Tuesday, July 18, 2017 - 3:55pm to 4:20pm
The pre-scrubbing system at the NCCC consists of a packed column, buffer tank, and a pump that recirculates sodium hydroxide solution from the buffer tank to the packed column. Flue gas exiting the upstream FGD from the main power generation facility flows through the pre-scrubber, which uses dilute caustic solution to remove a majority of the remaining SO2 from the flue gas. Concentrated sodium sulfate solution from the buffer tank is blown down to wastewater neutralization, while the cooled flue gas exits the pre-scrubber to a flue gas blower. The pre-scrubber column contains approximately 20 ft of Sulzer structured packing. The typical SO2 content of the flue gas feed to the pre-scrubber is 30 to 40 ppmv, which is typically scrubbed to about 1 ppmv at the outlet.
During prior baghouse modifications that took place at the E.C. Gaston power plant, the NO2 concentration entering the pre-scrubber decreased by an order of magnitude. In order to more effectively demonstrate the NO2 pre-scrubbing technology, modifications are being made at NCCC to inject NO2 (via a liquid N2O4 cylinder) into the flue gas piping upstream of the pre-scrubber to increase the inlet concentration. In addition to the artificial concentration increase on the inlet to the pre-scrubber, the accuracy of the outlet NO2 concentration measurement is being improved with the installation of a Rosemount CT5400 Continuous Gas Analyzer, which a lower detection limit of 0.05 ppmv (as compared to 1 ppmv for the previously installed analyzer).
Test objectives include, but are not limited to, the following:
- Measure the rate of sulfite oxidation in the liquid phase and measure the rate of SO2 absorption from the gas phase.
- Measure the steady state sulfite concentration as a function of thiosulfate and EDTA concentrations.
- Quantify thiosulfate consumption to define the economics of NO2 scrubbing with sulfite. Thiosulfate will be consumed via oxidation, and also lost to blowdown when caustic is replenished.
- Calculate the NO2 removal rate in the presence of steady state sulfite concentration in scrubbing solution via liquid and gas-phase measurements.
- Quantify metals present in solution that catalyze oxidation, if any.
The ratio of the rate of sulfite oxidation to the rate of NO2 absorption during the campaign is of particular importance to evaluating the feasibility of the technology. Although sulfite will be initially added to the pre-scrubber along with thiosulfate and EDTA, the steady-state sulfite concentration is a function of the SO2 concentration entering the pre-scrubber. Inlet and outlet SO2/NO2 concentrations will be analyzed continuously, while collected solvent samples will be analyzed on-site by iodometric titration, and back at The University of Texas lab via anion chromatography, to determine sulfite and thiosulfate concentrations.