(181as) Graphene Nanoscrolls Induced Crystallization of Polylactic Acid | AIChE

(181as) Graphene Nanoscrolls Induced Crystallization of Polylactic Acid

Authors 

Depan, D. - Presenter, University of Louisiana at Lafayette
Ajala, O., University of Louisiana at Lafayette
Werther, C., University of Louisiana at Lafayette
Nikaeen, P., University of Louisiana at Lafayette
Graphene nanoscrolls (GNS), one-dimensional carbon-based nanomaterials, have been predicted to possess extraordinary characteristics due to their unique open topology with scrolled graphene monolayers. In this study, the conversion of planar 2-D graphene nanoplatelets (GNPs) to tubular and scrolled 1-D GNSs is described. The effects of GNS as a nucleating agent to modulate the morphology, crystallization, and nano-mechanical properties of PLA were studied. The nucleating effect of GNS and its unique topological characteristics proves to influence the crystallization of PLA. FTIR indicated non-preferential interactions of PLA chains around GNS due to the bulky and helical PLA macromolecular chains. Superior interfacial interactions and strain in GNS provides better load transfer between GNS and PLA matrices, resulting in higher modulus and hardness. This study is the first detailed analysis to elucidate the role of unique GNS to favorably modulate the properties of a polymer.

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