(539e) Mechanistic Constitutive Model for Wormlike Micelle Solutions with Flow-induced Structure Formation

We present a tensor constitutive model for predicting stress and flow-induced structure formation in dilute wormlike micellar solutions. The micellar solution is treated as a dilute suspension of rigid Brownian rods whose length varies dynamically. Flow-induced alignment of the rods is assumed to promote increase of rod length that corresponds to the formation of flow-induced structures observed in experiments. At very high deformation rate, hydrodynamic stresses cause the rod length to decrease. If the rate constant for flow-induced rod growth is sufficiently large, the model predicts a multivalued relation between stress and deformation rate in both shear and uniaxial extension. Predictions for shear and extensional flow are in reasonable agreement with experimental results. By design, the model is simple enough to serve as a tractable constitutive relation for computational fluid dynamics studies of, for example, turbulent drag reduction.