(500c) Oxidative Coupling of Methane: The Role of the Tungstate Promoter in Mn-Na2WO4
Through careful fixed bed reactor studies using both Mn-Na2WO4 mixed oxide catalysts as well as individual manganese oxide and tungstate catalysts, we foundâin agreement with previous studiesâthat lattice oxygen of unpromoted Mn-oxide catalysts is effective for methane activation, but results in poor C2 yields since the undesired total oxidation dominates the surface reaction. The addition of the well-known promoter Na2WO4 improved reaction selectivity strongly by both suppressing CO2 formation and increasing C2H4 yield. Interestingly, however, we found the same improvement in C2 selectivity when using a simple physical mixture of separate Mn-oxide and Na2WO4 catalysts: Product distribution with the single, mixed oxide catalyst and the mixture of two pure metal oxides was experimentally indistinguishable. This contradicts the prevailing mechanism in the published literature that concludes that the promotion by tungstate is based on an exchange of lattice oxygen between the two metal phases.
A series of further kinetic tests and catalyst characterization performed to elucidate the role of Na2WO4 revealed that methane activation occurs exclusively on Mn-oxide, while Na2WO4 is essentially inactive towards all hydrocarbon species in the system but can be easily reduced by H2. The promotion of Mn-oxides by Na2WO4 hence does not rely on a lattice oxygen sharing mechanism but instead seems to be based on a concerted reaction mechanism in which the tungstate selectively removes H2 during the C2H6 dehydrogenation step in OCM. Thus, the combination of Mn-oxide and tungstate catalystsâeither in a single mixed oxide or a via physical mixture of two individual catalystsâsynergistically combines the methane activation over the Mn oxide, resulting in the formation of ethane, and the oxidative dehydrogenation of ethane to ethylene over the tungstate phase. Our results hence show that the currently prevailing understanding of the reaction mechanism over this catalyst is incomplete and opens a new direction for rational catalyst design for oxidative coupling of methane.