(442d) Investigation of Levoglucosan Decay in Wood Smoke Smog-Chamber Experiments: The Importance of Aerosol Loading, Temperature, and Vapor Wall Losses in Interpreting Results | AIChE

(442d) Investigation of Levoglucosan Decay in Wood Smoke Smog-Chamber Experiments: The Importance of Aerosol Loading, Temperature, and Vapor Wall Losses in Interpreting Results

Authors 

Nakao, S. - Presenter, Clarkson University
Levoglucosan has been extensively used as a molecular marker of biomass burning in source-apportionment studies over the last few decades. However, recent studies suggest that the atmospheric lifetime of levoglucosan may be in the order of only 1-2 days under summertime conditions relevant to prescribed/wildfires. Implications of levoglucosan reactivity to wintertime conditions, however, remain uncertain despite significant contributions of domestic wood combustion to wintertime air quality. This study presents smog chamber experiments to investigate levoglucosan decay during photo-oxidation of wood smoke over a temperature range between -10 and 10°C. Significant decay in particle wall-loss corrected levoglucosan is only observed around 10 °C in these experiments. Theoretical analysis shows that apparent chemical lifetime of levoglucosan increases at lower temperatures as well as at higher organic aerosol mass concentrations as a result of smaller vapor fractions. The chemical lifetime of a molecular marker is commonly interpreted by a relationship between relative decay in particle wall-loss corrected marker concentrations versus integrated OH exposure. However, this relationship strongly depends on vapor wall-loss rates in addition to temperature, organic aerosol concentrations, and OH concentrations. Therefore, inferred lifetimes from a small set of experiments from a single chamber cannot easily be generalized for the full range of atmospheric smoke conditions.