(142d) Plausible Pathway to Meet IMO 2020 Global Sulfur Cap
AIChE Annual Meeting
Monday, October 29, 2018 - 1:33pm to 1:54pm
Historically, marine fuel oil, also known as bunker fuel, is the atmospheric tower bottoms (ATB), which is the feedstock for the vacuum tower and is seldom available for fuel oil blending; thus the bunker fuel oil would typically be a blend of any of the following streams- low sulfur ATB, FCC slurry oil, hydrotreated gas oils, coker liquid, visbroken residue, deasphalted oil (DAO) etc. However, other studies indicate that, despite the fact that pricing of the blend components is an issue; the availability of the blend components that could meet the bunker fuel recipe in all geographic areas of the world is a greater problem. As for example, most of the low-sulfur crudes in the world are available outside the United States. Besides that, not all refineries have all the units or plants to produce the blend materials.
Typically, refiners fractionate the crude feed before hydroprocessing the different fractions. The heaviest fractions such as the ATB and vacuum resid (VR) that typically go into the bunker fuel recipe are the most difficult to hydroprocess. In this paper we explored an unorthodox option as a possible solution to meeting the demand of reduced sulfur bunker fuel market targeting the global limit of IMO - crude oil pretreatment through hydrotreating. The most common hydrotreater unit in a refinery may be used to produce low-sulfur blend material directly from whole crudes. This may eliminate the major capital cost of installing a new unit.
At the University of Tulsa Research Campus, we have a state-of-the-art large scale (4 to 4 ½ L) continuous hydroprocessing facility that could be operated up to 540°C and 27.6 MPa pressure. The present paper will discuss the unusual option of hydrotreating and subsequent fractionation of a whole crude oil with focus on the extent of Hydrodesulfurization (HDS) and Hydrodenitrification (HDN) of its ATB and/or VGO fractions. The experimental system was operated at 0.5 h-1 LHSV, 15.2 MPa and H2/oil ratio of 1200 L/L and 3 temperatures (335°C, 348°C and 357°C) using commercially available Nickel-Molybdenum on alumina catalyst. The feed and products were analyzed and bulk conversion of each contaminant as well as the density change is presented. The extent of HSD in the resulting products make them good candidates for blending materials to meet the target <0.5 wt% sulfur. The practicability of this option and other options will also be discussed.