(645h) Solid Dispersion Flow Battery Material Synthesis and Battery Characterization
AIChE Annual Meeting
2016
2016 AIChE Annual Meeting
Materials Engineering and Sciences Division
Materials for Electrochemical Energy Storage I
Thursday, November 17, 2016 - 10:28am to 10:44am
Within our research group, we have developed a flow battery that consists of a solid dispersion of particles in the electrolyte. This solid dispersion flow battery consists of solid particles, and thus has the improved energy density that comes with bypassing the solubility limitations of conventional flow batteries. However, in contrast to many other semisolid flow batteries reported in the literature, by avoiding the use of carbon additives the viscosity is kept much lower in these fluids. The tradeoff of having a lower viscosity is that the power density is lower because electrochemical reactions proceed via collisions with the current collector, rather than throughout and interconnected carbon structure.
In this talk, recent efforts in our group to synthesize and characterize materials for the solid dispersion flow battery will be described. In particular, we have developed a scalable templated synthesis of active material nanoparticles of lithium-ion battery cathode materials that are electrochemically active and small enough to remain stably dispersed within the flow battery electrolytes. Recent efforts to characterize and understand the electrorheological coupling within this system, and the limits of the power capability within the flow battery architecture, will also be discussed.