(492d) Electrochemical Carbon Dioxide Reduction As an Alternative Source of Fuels and Chemicals | AIChE

(492d) Electrochemical Carbon Dioxide Reduction As an Alternative Source of Fuels and Chemicals


Cave, E. - Presenter, Stanford University
Kuhl, K., Opus 12
Diaz, D., Opus 12
Cost-effective industrial CO2 recycling using renewable energy sources (ECO2R) could form the basis of an artificial carbon cycle that replaces a wide range of products that are currently derived from fossil resources. ECO2R combines CO2, water, and electricity, and converts them into useful products using engineered metal catalysts. At full scale, this technology could eliminate our dependence on fossil resources by providing an alternative source of carbon-based compounds for fuels and commodity chemicals. However, commercial fuel and chemical production via ECO2R is challenging, because the current state of the technology is not cost-effective enough to compete with conventionally manufactured fuels and chemicals already on the market.

The key cost-drivers of ECO2R are the energy efficiency, product selectivity, and current density. Based on these metrics, we have developed a model for the cost of ECO2R-derived compounds. We will use the model to compare the cost of ECO2R derived compounds to fuels and chemicals derived from traditional sources. In doing so, we will identify the technical barriers that need to be overcome to reduce the cost, including enhanced electrocatalysis [1-3] and achieving high current densities needed for a cost-competitive process because of limited carbon dioxide solubility.

Opus 12 has also developed a prototype ECO2R reactor. The Opus 12â??s prototype contains improved catalysts and a reactor design with high energy efficiency, high product selectivity and high current densities. We will present our technical progress in terms of these key performance metrics. Using these metrics, we can estimate the current cost of ECO2R and present a roadmap of improvements needed to further reduce costs to compete with traditional chemicals and fuels derived from fossil resources.

[1] K.P. Kuhl, E.R. Cave, D.N. Abram, T.F. Jaramillo, New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces, Energy Env. Sci., 5 (2012) 7050-7059.

[2] K.P. Kuhl, T. Hatsukade, E.R. Cave, D.N. Abram, J. Kibsgaard, T.F. Jaramillo, Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces, Journal of the American Chemical Society, 136 (2014) 14107-14113.

[3] F.S. Roberts, K.P. Kuhl, A. Nilsson, High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts, Angewandte Chemie International Edition, 54 (2015) 5179-5182.