(312e) Conductivity Degradation of Polyvinylidene Fluoride Binder during Cycling: Measurements and Simulations for Lithium-Ion Batteries
- Conference: AIChE Annual Meeting
- Year: 2016
- Proceeding: 2016 AIChE Annual Meeting
- Group: Transport and Energy Processes
- Time: Tuesday, November 15, 2016 - 10:15am-10:40am
We will present experimental characterization of the polymer binder for battery applications. Mechanical properties of the composite binder will be shown for both dry films and also binder swollen with carbonate electrolytes used in rechargeable lithium batteries. The electrical properties are strongly dependent on the applied stress. The evolution of mechanical and electrical properties of the binder after repeated cycling will be shown.
Then we will examine the impact of cyclic mechanical stresses on the performance of lithium cobalt oxide cathodes. Experimental results will be presented on the evolution of electrical conductivity as a function of mechanical cycling. Mechanisms for electronic conductivity in these complex porous composite electrodes will be investigated using mesoscale simulations using experimentally determined three dimensional structures of battery cathodes. Implications for battery internal resistance and cycling stability will be discussed.
Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energyâ??s National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2016-4371 A