(459a) Dopant Effect on Perovskite Based Mixed Metal Oxides for Chemical Looping with Oxygen Uncoupling (CLOU)
- Conference: AIChE Annual Meeting
- Year: 2015
- Proceeding: 2015 AIChE Annual Meeting Proceedings
- Group: Innovations of Green Process Engineering for Sustainable Energy and Environment
- Time: Wednesday, November 11, 2015 - 8:30am-8:55am
As an alternative to conventional combustion, chemical looping combustion (CLC) has the potential to achieve higher 2nd law efficiency with inherent CO2 capture capabilities. Although CLC has been extensively demonstrated for gaseous fuels, extension of this process to solid fuels, such as coal, is challenging due to the slow kinetics of solid-solid reactions. Chemical Looping with Oxygen Uncoupling (CLOU) provides a possible solution to this challenge. In a CLOU process, lattice oxygen from the oxygen carrier is released into the gas phase for facile combustion of solid fuels. The oxygen deprived oxygen carrier is then regenerated with air while producing heat. In the current study, perovskite-structured oxygen carriers with a general formula of AxA’1-xMnO3 (A/A’ = Sr, Ca, Ba) are investigated for CLOU applications. Results show CaMnO3 provides excellent oxygen uncoupling ability; however, irreversible phase decomposition is observed. The effects of Sr and Ba as A-site dopants on CaMnO3 are explored with the primary intention to prevent irreversible phase decomposition. These materials are tested for oxygen release properties, redox stability, and reactivity. It was determined that both barium and strontium doping lead to decreased oxygen release at high temperatures. Furthermore, Sr dopant exhibits excellent compatibility with the CaMnO3 parent structure at a wide range of concentrations. Ca1-xSrxMnO3 is also able to reduce the initial oxygen release temperature by over 400oC, enabling facile oxygen donation. With the goal of understanding the effect of A-site cation in perovskite based oxygen carriers, DFT calculations were performed to determine the vacancy formation energy for these perovskite materials. DFT results indicate CaMnO3 requires less energy to create an oxygen vacancy whereas Ba stabilizes lattice oxygen in the perovskite structure. The finding is used to explain CLOU properties of the aforementioned oxygen carriers and to guide future efforts to improve oxygen carriers.