(436b) Low Molecular Weight CO2 Thickener Design for Enhanced Oil Recovery

Authors: 
Enick, R., University of Pittsburgh
Lee, J. J., University of Pittsburgh
Perry, R. J., Global Research, General Electric
Doherty, M., Global Research, General Electric
O'Brien, M., Global Research, General Electric
Dhuwe, A., University of Pittsburgh
Cummings, S., University of Bristol
Beckman, E. J., University of Pittsburgh

The low viscosity of CO2 at typical enhanced oil recovery (EOR) conditions is responsible for a poor mobility ratio that causes viscous fingering and poor sweep efficiency, leading to reduced efficiency and yield. To overcome this problem, there is a need to develop CO2-soluble additives that will increase the effective viscosity of CO2 without the use of a co-solvent. The only known polymeric direct thickener poly(fluoroacrylate-co-styrene) (polyFAST) has been shown to significantly increase the viscosity at dilute concentrations (<1wt%) measured by falling cylinder viscometry and Berea sandstone core mobility experiments. However, high molecular weight polymers like polyFAST require significant amounts of expensive fluorinated moieties in order to impart solubility. In addition to their cost, fluorinated compounds have undesirable environmental impacts. Therefore, we are exploring non-fluorous, self-associating, low molecular weight thickeners as a potentially safer and more economically viable route to thickening CO2.

A brief history of prior attempts to thicken CO2 with either high molecular weight polymers or small associating compounds is presented. Our strategy for designing a novel small molecule CO2 thickener is then detailed along with phase behavior and viscosity of dilute solutions composed of thickener candidates in either pure CO2.or CO2-rich environments. Each thickener candidate is assembled with both CO2-philic segments (e.g. an oligomer or low molecular weight polymer of dimethyl siloxane or propylene glycol, sugar acetate) to impart favorable solvent-solute interactions and CO2-phobic functional groups (e.g. aromatics, hydroxyl aluminum, tin fluoride, carboxylic acid, benzoic acid, hydroxyl groups, amides) that induce associative intermolecular interactions (e.g. aromatic dimerization, hydrogen bonding, Lewis acid-base interaction) which can lead to the formation of viscosity-enhancing supramolecular structures in solution.