(65d) A Facile Microwave-Assisted Route to Co(OH)2 and Co3O4 Nanosheet for Li-Ion Battery

Chen, G., New Mexico State University
Luo, H., New Mexico State University

Cobalt hydroxide (Co(OH)2), as one of the most important functional inorganic materials, can be used in the field of catalysis and electrochemical electrodes. The previous report revealed that Co(OH)2 is a promising alternative conversion-based anode materials for lithium-ion batteries (LIBs) due to its high capacity. Unfortunately, like other conversion-based anode materials, the implementation in LIBs is greatly hampered by its poor cycling performance. One of the most promising strategies to tackle this obstacle is to make Co(OH)2 into sheet-like structure to improve the structural stability in the electrochemical reactions. Compared with the bulk Co(OH)2, Co(OH)2nanosheet displays obvious advantages due to large surface area, highly oriented growth direction, tunable interlayer space for the de/insertion of lithium ions.

In this work, a facile microwave-assisted synthetic route has been successfully developed for preparing hexagonal Co(OH)2 nanosheets with average width of 2 μm and thickness of 100 nm. Co(OH)2 can further convert to porous Co3O4nanosheets via thermal decomposition. Their phases, structures and morphologies were investigated by X-ray diffraction (XRD), atomic force microscopy (AFM), and transmission electron microscopy (TEM). Both Co(OH)2 and Co3O4 nanosheets can serve as potential candidates for anodes of Li-ion battery. The electrochemical study revealed that Co(OH)2 and Co3O4 nanosheets delivered a reversible capacity of 600 and 700 mAh g-1 after 40 cycles, respectively. Cyclic voltammetry (CV) curves also confirmed the relative stability of the as-synthesized electrode materials. This effective microwave-assisted route may be a promising approach for preparing other transition metal hydroxide/oxides for energy applications.


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