(395t) Microwave Synthesis and Characterization of MOF-74 (M = Ni, Mg) for Gas Separation

Authors: 
Wu, X., New Mexico State University
Bao, Z., Zhejiang University
Yuan, B., New Mexico State University
Wang, J., New Mexico State University
Sun, Y., New Mexico State University
Luo, H., New Mexico State University
Deng, S., New Mexico State University



Isostructural MOF-74 (M = Ni, Mg) were successfully synthesized with both hydrothermal method (1 and 3) and microwave-assisted method (2 and 4). These MOF-74 samples were characterized with scanning electron microscopy for crystal structure, powder X-ray diffraction for phase structure, and nitrogen adsorption for pore textural properties. The experimental results showed that MOF-74 samples synthesized by the microwave-assisted method have a smaller particle size with relatively more uniform particle size distribution. The microwave effects also helped to produce a larger specific surface area and micropore volume, with a similar median pore diameter. Adsorption equilibrium and kinetics of various gases (CO2, CH4, N2, C2H4, C2H6, C3H6 and C3H8) on these MOF-74 samples were determined at 298 K and gas pressures up to 1 bar. Adsorption equilibrium selectivity (α), combined equilibrium and kinetic selectivity (β), and adsorbent selection parameter for pressure swing adsorption processes (S) were estimated. The relatively high values of adsorption selectivity indicates the potential to separate CO2/CH4, CO2/N2, C2H4/C2H6, C3H6/C3H8 and C3H6/C2H4 pairs in a vacuum swing adsorption process using the MOF-74 adsorbent. The microwave-assisted method was found to improve MOF-74 with a larger adsorption capacity and higher selectivity for gas separation.

Checkout

This paper has an Extended Abstract file available; you must purchase the conference proceedings to access it.

Checkout

Do you already own this?

Pricing


Individuals

AIChE Members $150.00
AIChE Graduate Student Members Free
AIChE Undergraduate Student Members Free
Non-Members $225.00