(587d) Hydrogen Production by Reforming of Natural Gas Over Ni Based Perovskite Type Catalysts
AIChE Annual Meeting
2012
2012 AIChE Annual Meeting
2012 International Congress on Energy (ICE)
Renewable Hydrogen Production
Wednesday, October 31, 2012 - 4:15pm to 4:35pm
Hydrogen Production by reforming of natural gas over Ni based perovskite type catalysts
Dong Ju Moona,b*, Eun-Hyeok Yanga,b, Su Hyun Cho a,c, Seung Hoon Kima,c, Yun Ju Leea, Kannapu Hari Prasad Reddya, Sang Woo Kima,b and Byong Sung Ahna
aClean Energy Research Center, KIST, Seoul , South Korea
bClean Energy & Chemical Engineering, UST, Daejeon, South Korea
cDepartment of Chemical & Biological Engineering, Korea University, Seoul, South Korea
Corresponding Author’s Email : djmoon@kist.re.kr
Steam CO2 reforming of methane over Ni-based perovskite type catalyst was investigated to produce hydrogen-rich gas for applications in hydrogen station and fuel cell process. Ni-based perovskites were prepared by the Pechini method and calcined in air. The catalysts before and after the reaction were characterized by N2physisoprtion, CO chemisoprtion, XRD, TPR, SEM and TEM techniques. To obtain hydrogen-rich gas, simulations for SCR and SR were carried out by commercial simulation program, and catalytic performance was evaluated in a fixed bed reactor system using feed ratio estimated by simulation. The results suggest that the hydrogen-rich syngas produced by SCR and SR of methane can be applied to SOFC and MCFC systems.
Keywords : SCR, Perovskite, Strontium
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