(20h) Three Step Approach for Characterization of Non – Ideal Flows in Chemical Reactors

A
THREE STEP APPROACH FOR CHARACTERIZATION OF NON ? IDEAL FLOWS IN CHEMICAL
REACTORS

Introduction

The
concept of non-ideal flow in reactors is taught in the Under ? Graduate (UG) curriculum
at IIT Madras via theory lectures and laboratory tracer experiments. The difference
in the Residence Time Distribution (RTD) profile measured in the lab, and the
ideal RTD profiles for CSTRs and PFRs, is used to illustrate the effect of
?real' or non-ideal flow in reactors, on RTD. In this work, we propose a
different methodology for teaching the concepts of non-idealities in flow
reactors, and residence time distributions. The focus here is on providing a
more visual basis for the concepts, thus enhancing students' understanding, and
comfort levels.

Methodology

First,
it is proposed that a visual tracer material be used in the laboratory reactor,
and snapshots of the movement of the tracer through the reactor be taken at
several instants of time, at a host of nominal operating conditions. Next, the
routine tracer experiment involving the measurement of outlet tracer
concentrations, and evaluation of the RTD profile from the same, is to be
performed. The non-idealities such as bypassing, dead volumes, re-circulating
zones, etc. can be observed in the snapshots, whereas the impact of these on
RTD profiles can be directly analyzed via the second experiment.

Next,
it is proposed that Computational Fluid Dynamics (CFD) simulations of the same
reactor be performed by the students. The steady-state CFD simulations will provide
rich information regarding velocity contours all over the reactor while the
unsteady simulations give the species contour information at various instants
of time. This can be linked to the visual tracer snapshots, for validation, and
also, for further understanding. A ?numerical' tracer experiment may then be
performed in CFD, using established procedures, to obtain a CFD-predicted RTD
profile. This is easily validated against the experiments above.

Analysis

With
these four pieces of information, it will be very easy to illustrate concepts
to the students. In the past year, we have used this methodology and analyzed a
stirred flow reactor of dimensions 21 cm height and 16cm in diameter that is in
the Chemical Engineering Lab here. The specific operating conditions, at which
bypassing and dead zones (among other non-idealities) are clearly
visible, were identified. This was used to illustrate the connection between
RTD and non-idealities, very successfully.

In
the third year UG class on Chemical Reaction Engineering, the method was
demonstrated to the group of 70 students in April 2012. Their performance on
tests was found to improve, and their understanding of the concepts deepened
after the visual tracer and CFD results were shown to them. In the future, we
expect that such CFD simulations should become a routine part of the UG
curriculum, due to its increased importance as a design tool. We believe that
this simple methodology therefore has the potential to significantly alter
student's perspective on reactor modeling, in the future years.

Preliminary
results

The
dimensions of the cylindrical Continuously Stirred Tank Reactor (CSTR) are:
Length (L) = 17cm & Diameter (D) = 16cm. The impeller is at a distance of
5cm from the bottom of the reactor. The dimensions of the impeller blade are:
width = 0.2cm, height = 0.5cm & depth = 2.4cm. The radius of the inlet is
2.5cm and is present at a distance of 4cm from the bottom of the tank. The
geometry is shown in figure 1.

Figure 1: Schematic of the
laboratory CSTR

Experimental
and CFD studies were carried out on the reactor. To illustrate a case of
bypassing, the study in which stationary impeller results in bypassing has been
shown here. Figure 1
shows the snapshots taken from the visual tracer experiment at various
intervals of time. Figure 2 gives the snapshots of the tracer along a plane
containing the inlet and the outlet, at similar instants of time. These
snapshots seem to match the visual tracer ones in Figure 1. The virtual RTD
carried out using CFD results in a sharp peak initially signifying bypassing.

Each
of these tools helps in analyzing the system better. The visual tracer
experiments help us in determining the non- ideality visually without being
able to quantify it. The CFD results help in quantifying the non-ideality and
determining its exact location in the reactor. CFD is used for optimum
designing of chemical reactors. The experimental RTD when compared with the
ideal one gives an idea of the deviation from the ideality.

Figure 2: Bypassing seen in
visual tracer experiment

Figure 3: Bypassing seen in CFD
simulations

Figure 4: RTD of the reactor
showing bypassing

Keywords:
Residence Time Distribution, Computational Fluid Dynamics, Bypass, Dead zone,
Re-circulation.