(575h) Dynamic Regeneration of NOx Storage Catalyst - Modeling Study | AIChE

(575h) Dynamic Regeneration of NOx Storage Catalyst - Modeling Study

Authors 

Stepanek, J. - Presenter, Institute of Chemical Technology, Prague
Plat, F. - Presenter, Prague Institute of Chemical Technology
Marek, M. - Presenter, Institute of Chemical Technology, Prague
Kubicek, M. - Presenter, Institute of Chemical Technology, Prague


Current research extends the knowledge of the regeneration mechanism of periodically operated NOx-storage catalytic converters (lean NOx traps, LNTs). This advance makes possible to develop more accurate mathematical models of the chemical processes taking place in the converter, which are now able to describe not only the quantity and selectivity of reaction products, but also the effects of dynamically altered inlet conditions. These effects could not be simulated in detail using previous models. This study focuses on the differences in the qualitative performance of several reaction mechanisms for the LNT regeneration, and particularly on their ability to describe the effects of regeneration length and inlet gas composition on the conversion and selectivity of NOx reduction.

References:

P. Koci, F. Plat, J. Stepanek, M. Kubicek, M. Marek: Dynamics and selectivity of NOx reduction in NOx storage catalytic monolith. Catalysis Today, (2008), in press. DOI:10.1016/j.cattod.2007.11.023

L. Cumaranatunge, S.S. Mulla, A. Yezerets, N.W. Currier, W.N. Delgass, F.H. Ribeiro: Ammonia is a hydrogen carrier in the regeneration of Pt/BaO/Al2O3 NOx traps with H2. Journal of Catalysis, 246, (2007), 29-34. DOI:10.1016/j.jcat.2006.11.008

A. Guethenke, D. Chatterjee, M. Weibel, N. Waldbuesser, P. Koci, M. Marek, M. Kubicek: Development and application of a model for a NOx storage and reduction catalyst. Chemical Engineering Science, 62, (2007), 5357-5363. DOI:10.1016/j.ces.2007.01.049

P. Koci, M. Schejbal, J. Trdlicka, T. Gregor, M. Kubicek, M. Marek: Transient behaviour of catalytic monolith with NOx storage capacity. Catalysis Today, 119, (2007), 64-72. DOI:10.1016/j.cattod.2006.08.014

A. Guethenke, D. Chatterjee, M. Weibel, B. Krutzsch, P. Koci, M. Marek, I. Nova, E. Tronconi: Current status of modeling lean exhaust gas aftertreatment catalysts, in "Advances in Chemical Engineering vol. 33: Automotive Emission Control", pp. 103-211, ed. G. B. Marin, ISBN: 978-0-12-373900-1, Elsevier 2007. DOI:10.1016/S0065-2377(07)33003-2

J. Jirat, M. Kubicek, M. Marek: Mathematical modelling of catalytic monolithic reactors with storage of reaction components on the catalyst surface. Catalysis Today, 53, (1999), 583-596. DOI:10.1016/S0920-5861(99)00146-7

www.vscht.cz/monolith