(546a) Nafion/Acid Functionalized Zeolite Beta Nanocomposite Membrane for High Temperature Pemfcs

Authors: 
Chen, Z. - Presenter, University of California, Riverside
Holmberg, B. A. - Presenter, University of California, Riverside
Li, W. - Presenter, University of California, Riverside
Wang, X. - Presenter, Department of Chemical and Environmental Engineering, University of California, Riverside
Munoz, Jr., R. A. - Presenter, University of California, Riverside
Yan, Y. - Presenter, University of Delaware


Nafion/Acid Functionalized Zeolite Beta (NAFB) nanocomposite membrane has been successfully prepared by in situ hydrothermal crystallization method. The Acid Functionalized Zeolite Beta (AFB) nanocrystals less than 20 nm were formed and embedded into the Nafion matrix. The physico-chemical properties of all membranes were investigated regarding their tensile strength, water uptake and thermogravimetric analyzer (TGA). The proton conductivity commercial Nafion membrane and the NAFB composite membrane were measured with different relative humidity (RH) at 25, 80, 120 oC. Compared with commercial Nafion membrane, the NAFB composite membrane has much higher proton conductivity at 120 oC and reduced RH. NAFB composite membrane and commercial Nafion membranes were also studied in an H2/O2 PEMFC over a wide range of RH values from 25 to 100% at temperatures of 80 and 120°C. The NAFB composite membrane showed a pronounced improvement over commercial Nafion membranes when operated at 120 °C and reduced RH. The high performance of the NAFB composite membranes at low RH was attributed to improved water retention due to the presence of absorbed water species within the pores and on the surface of AFB. NAFB composite membranes have the potential for use with high temperature PEMFC.