CCPS Process Safety Glossary | AIChE

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CCPS Process Safety Glossary

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Proteomics

the study of protein functions and structure by organisms.

Protocol (Audit)

A document that organizes audit procedures into a general sequence of audit steps and describes the actions to be taken by the auditor.

Protocol (Regulated Product Development)

Documentation that ties together all SOPs (standard operating procedures) to direct the work performed in a regulated facility; who approves what, who is allowed to sign off on materials and products, where certain files and documents are kept, and so on; also a detailed plan for a clinical trial, stating (among other things) the trial's rationale, purpose, scope, dosages, routes of administration, length of study, and eligibility criteria.

Protozoa

Single-celled organisms, many of which are parasitic (for example, the malaria parasite).

Proximate Cause

The cause factor which directly produces the effect without the intervention of any other cause. The cause nearest to the effect in time and space.

PSM Audit

An activity to determine and status and quality of a PSM program. This term is not used to describe an audit performed exclusively in response to OSHA's PSM Standard, but to an audit of any PSM program.

Public Emergency Exposure Limit (PEEL)

The maximum concentration in air of a toxic material to which the public might be exposed without significant adverse impacts in the event of an accident.

Puff

A cloud of pollutants resulting from a nearly instantaneous or short duration release.

Puff Release

See Instantaneous Release.

Purge Gas

A gas that is continuously or intermittently added to a system to render the atmosphere noncombustible. The purge gas can be inert or combustible.

Purging

The removal of oxygen from a closed system (equipment and piping) to below the LOC of the particulate solid by means of applying pressure, vacuum, and/or a purge gas.

Pyrophoric

A chemical that will ignite spontaneously in air at a temperature of 130 F (54.4 C) or below. [Note that definitions of pyrophoric from other sources may specify a time frame, usually seconds or minutes, within which ignition must be observed.] OSHA 1994

Pyrophoric Gas (NFPA 55)

A gas that will spontaneously ignite in air at or below a temperature of 130 F (54 C).

Pyrophoric Particulate Solid

A particulate solid that undergoes such vigorous oxidation or hydrolysis (often with evolution of highly flammable gases) when exposed to atmospheric oxygen or to water, that it rapidly ignites without an external source of ignition. This is a special case of spontaneous combustion.

Qualitative

Based primarily on description and comparison using historical experience and engineering judgment, with little quantification of the hazards, consequences, likelihood, or level of risk.

Qualitative Methods

Refers to the method of evaluation gained through experience (e.g., application, operation, support) or essential, required and desirable features.

Qualitative Risk Analysis

Based primarily on description and comparison using historical experience and engineering judgment, with little quantification of the hazards, consequences, likelihood, or level of risk.

Quality Assurance

A planned, systematic pattern of actions necessary to provide suitable confidence that a system or component will perform satisfactory in actual operation. A systematic pattern of actions throughout design and production, to ensure confidence in a product's conformance with specifications. A set of systematic actions intended to provide confidence that a product or service will continually fulfill a defined need.

Quality Assurance (QA)

Activities performed to ensure that equipment is designed appropriately and to ensure that the design intent is not compromised, providing confidence throughout that a product or service will continually fulfill a defined need the equipment's entire life cycle.

Quality Assurance (QA)

Activities performed to ensure that equipment is designed appropriately and to ensure that the design intent is not compromised, providing confidence throughout that a product or service will continually fulfill a defined need through the equipment's entire life cycle.  

Quantitative Methods

Refers to the method of evaluation obtained through measurement or mathematical analysis of essential, required and desirable features. Refers to the method of evaluation gained through measurement or mathematical analysis of essential, required and desirable features.

Quantitative Risk Analysis (QRA)

The systematic development of numerical estimates of the expected frequency and severity of potential incidents associated with a facility or operation based on engineering evaluation and mathematical techniques.

Quantitative Risk Assessment (QRA)

The use of Quantitative Risk Analysis results to make decisions, either through relative ranking of risk reduction strategies or through comparison with risk targets.

Quantitative Risk Assessment (QRA)

A quantitative evaluation of the overall risk, determined by combining the frequencies and consequences of potential incident scenarios.

Quench Drum

A vessel with internal liquid sprays supplied by an external recirculation pump loop with a quenching liquid sprayed directly into the vapor space to contact, cool, and condense at least part of the hot vented gas or vapor stream before these gases enter the main vent header system.

Quench Pool

A closed vessel containing a relatively large volume of liquid. The emergency vent stream is sparged subsurface through the liquid volume at high velocity, resulting in vigorous agitation and circulation of the pool contents in order to maximize cooling and condensation or reaction with the pool liquid. Most or all of the vented stream can be captured; residual vapor and non-condensable gas may be released to the vent header system for further treatment or disposal.

Quenching

Rapid cooling from an elevated temperature, e.g., severe cooling of the reaction system in a short time (almost instantaneously), "freezes" the status of a reaction and prevents further decomposition or reaction.

Quenching Diameter

The largest diameter of a cylindrical tube that will just quench (extinguish) the flame front of a particular fuel-air mixture

Quenching Distance

The distance between two parallel plates (flat walls) that will just quench (extinguish) the flame front of a particular fuel oxidant mixture. It is smaller than the quenching diameter in cylindrical tubes.

Quenching Length

The length of a flame arrester element necessary to quench a high speed flame.

Radiant Heat

The heat transferred from one body to another not in contact with it but by means of wave motion through space.

Radio Frequency Interference (RFI)

Any electrical signal capable of being propagated into and interfering with the proper operation of electrical or electronic equipment. The frequency range of such interference may be taken to include the entire electromagnetic spectrum. Type of electrical noise that can affect electronic circuits adversely.

Rain Out

When a superheated liquid is released to the atmosphere, a fraction of it will flash into vapor. Another fraction may remain suspended as an aerosol. The remaining liquid, as well as portions of aerosol, may "rain out" on the ground.

Random Access Memory (RAM)

Memory that allows the user to read or write into in approximately the same length of time.

Random Demands

Where the time or approximate time of the demand occurrence is predictable, the primary concern is whether the ESD system is operational at that time. In other words, the criteria is related to the cumulative probability of failure of the ESD system over the appropriate time interval which ends with the occurrence of the demand.

Rare event

An event or incident whose expected frequency is very small. The event is not statistically expected to occur during the normal life of a facility or operation.

Rate of Reaction

The rate at which the conversion of reactants takes place. The rate of reaction (r) is a function of concentrations (F(c)) and the reaction rate constant (k): r = koF(cA,cB,...,cX). The heat (q) produced by a reaction is a linear function of the rate of reaction which makes the rate of reaction a basic parameter in determining the required cooling capacity during all stages of the reaction process.

Raw Data

The original records from which reliability data is extracted; the facility records of equipment failure, repair, outage, and exposure hours or demands which require analysis and encoding in order to be placed into data elements.

Raw Plant Data

Untreated field-equipment-specific failure information often collected as part of plant operating and maintenance records, required as input for preparing plant-specific failure rate data.

Reactants

Chemicals that are converted into the required products during the reaction process.

Reaction

Any transformation of material accompanied by a change of enthalpy which may be endothermic or exothermic. (ASTM E 1445)

Reaction Induction Time (RIT)

The time a chemical compound or mixture may be held under isothermal conditions until it exhibits a specific exothermic reaction. (ASTM E 1445)

Reaction Kinetics

The complex of data (thermodynamic and kinetic), that determine a reaction.

Reaction Rate Constant

The constant k in the rate of reaction. The reaction rate constant is the function of temperature as represented by the Arrhenius equation.

Reactive Chemical

A substance that can pose a chemical reactivity hazard by readily oxidizing in air without an ignition source (spontaneously combustible or peroxide forming), initiating or promoting combustion in other materials (oxidizer), reacting with water, or self-reacting (polymerizing, decomposing or rearranging). Initiation of the reaction can be spontaneous, by energy input such as thermal or mechanical energy, or by catalytic action increasing the reaction rate.

Reactive Groups

Categories of chemicals that react in similar ways, often because they are similar in their chemical structure. (NOAA 2002)

Reactive Substance/Material

Substance or material which enters into a chemical reaction with other stable or unstable material.

Reactivity

The relative tendency of a substance to undergo chemical reaction (low, medium, or high).

Reactivity, Chemical

See chemical reactivity.

Read Only Memory (ROM)

Memory that allows the user to read from but not to write into.