(758e) First Detection and Characterization of Super-Electrophilic Metal (Pt+2, Pd+2, Ag+) Cations in Zeolite SSZ-13: Novel Chemistry for Adsorption and Catalysis Applications
With aid of FTIR and DFT, we unravel the novel chemistry of Pd+2/SSZ-13 and its complexes with CO, NO, C2H4. We also show the first example of comprehensive modeling of a Pd(Pt)/zeolite system including the interaction with the small molecules (CO,NO,ethylene) â these interactions are of great importance for adsorption (e.g., PNA) and catalysis (ethylene transformations) [1,2].
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