(43i) Active Compressibility | AIChE

(43i) Active Compressibility

Authors 

Dulaney, A. - Presenter, The University of Texas at Austin
Mallory, S., Caltech
Brady, J., California Inst of Technology
Active systems possess the unique ability to separate into dense and dilute phases without attractive interactions. Determining aspects of their phase behavior is an on-going challenge as they are far from equilibrium, barring the use of existing thermodynamic frameworks. However, mechanical and structural order parameters remain viable options for probing these systems. Using a combination of large-scale simulation and analytic theory, we demonstrate that the mechanically defined compressibility acts as a thermodynamic-like response function in suspensions of active disks. As such, the compressibility captures aspects of active phase separation and provides a means through which mechanical, structural, and "thermodynamic" quantities can be related in these systems. This connection provides an alternate perspective regarding the existence of an active analogue to chemical potential.