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Chem Economics: ACC Releases Portfolio of Specialty Chemicals Indexes

September
2012
Chem Economics
T. Kevin Swift
The American Chemistry Council (ACC) has launched a new set of indexes covering nearly 30 segments of the U.S. specialty chemicals market. (The first, which dealt with plastic additives, was discussed in the July issue, p. 13.) This is the first set...

Safety Incidents in Ethylene Plants

Mar 23, 2010
Stephen De Haan
Many similar safety incidents occur in ethylene plants throughout the world. While these should be well known to plant operators, our paper lists these more common safety incidents along with their root causes. We then discuss several less common safety incidents that have occurred: • Heater over-...

Technologies for Enhancing Refinery Gas Value

Mar 23, 2010
The trend of processing heavy and sour crude is resulting in 'fuel long' refineries which seek to export energy in the form of refinery fuel gas or are looking for other ways to extract value from the fuel gas system. There are common solutions that either are applicable to a few selected high-...

Ethylene Unit Hydrocarbon Release and Fire, Sunoco Marcus Hook, PA Refinery

Mar 23, 2010
Arthur Jensen
At approximately 10:15 p.m. on Sunday, May 17, 2009, there was a sudden and large hydrocarbon release from a main process pipe in the Ethylene Unit at the Sunoco Marcus Hook, Pennsylvania Refinery. The release found an ignition source at an operating process furnace within 2 seconds, resulting in a...

Current Methods of Measurement of NO, NO2 and NH3

Mar 23, 2010
Dwight Hines
The measurements of NO, NO2 and NH3 have been a challenge for analytical chemists for many years. This paper will deal primarily with new advances in technology for on-line NO and NO2 analysis using the paper tape technology from CI Analytics. The evolution of the instrument from CI Analytics will...

Advanced Catalysts for C2-C4 Selective Hydrogenation

Mar 22, 2010
Dr. Ernesto Angueira
Availability of pure olefin monomers is a key step in the production of polymers. These olefins are mainly produced by steam crackers. KataLeuna offers a wide range of catalysts and adsorbents to purify the various steam cracker cuts. This contribution will report on the latest catalyst...

TLE Steam Side Corrosion Boiler Feed Water & TLEs : Avoiding Failures

Mar 22, 2010
Jos Vankevelaer
This paper shows on the one hand an analysis of sudden failures occurring at the bottom section of the TLEs, caused by corrosion at the steam side and an overview of the proposed corrective actions. On the other hand best practices during operations and shutdown are presented to avoid such damages...

Deployment of ZeaChem's Sustainable Biorefinery

Mar 22, 2010
Tim Eggeman
Increased emphasis is being placed on renewable, sustainable, domestic forms of energy, including transportation fuels, at national, state and local levels. Successful deployment of alternative solutions to petroleum-based liquid fuels for the transportation industry is dependent upon technical,...

Reliable Retention of Molecular Sieve Beds

Mar 22, 2010
Robert Norell
Reliable operation of an Olefin gas/liquid dehydrator requires careful attention to the integrity of the grid supporting the molecular sieve. Problems with retention of the sieve can stem from many points in the design, fabrication, and installation process for these assemblies. Two case studies...

Holistic Approach to the Revamping and De-Bottlenecking of Pre-Heat Trains

Mar 22, 2010
Graham T. Polley
The energy efficiency and throughput of pre-heat trains can be improved by using process integration and through fouling mitigation. In this paper we show how the approaches can be combined in a systematic way. If fouling behaviour is ignored the use of process integration can lead to revamps in...

Unusual Corrosion Failures of Transfer Line Exchangers

Mar 22, 2010
Pinakin Mistry
This paper describes two case histories of corrosion failures. The first case history describes metal dusting of the tubes and tubesheet from the process side in the horizontal TLE. The tubesheet of TLE was overlayed with Alloy 625 to prevent erosion. Deposition on the waterside allowed higher than...

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