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Chem Economics: ACC Releases Portfolio of Specialty Chemicals Indexes

September
2012
Chem Economics
T. Kevin Swift
The American Chemistry Council (ACC) has launched a new set of indexes covering nearly 30 segments of the U.S. specialty chemicals market. (The first, which dealt with plastic additives, was discussed in the July issue, p. 13.) This is the first set...

Fouling by Asphaltenes After and During Conversion

Mar 23, 2010
Irv Wiehe
During resid conversion processes, such as visbreaking or hydroconversion, more saturated pendant groups are cracked off asphaltenes, making them less soluble. Meanwhile, the more saturated volatile liquids formed during the conversion are often nonsolvents for asphaltenes. As a result, these...

Furnace Safe Park DCS Tool

Mar 23, 2010
Bryan McVicker
Properly managing the shutdown or “safe parking” of multiple steam-cracking furnaces during a plant-wide upset can be challenging. Alarm flood and multiple competing demands on operators are characteristics of such situations. The ExxonMobil Beaumont olefins plant has created a DCS interface to...

Possible Solutions for Reducing NOx and SOx Emissions from Large Cargo Ships

Mar 23, 2010
Reggie Zhan
In an attempt to curb air pollution from the shipping industry, the U.S. Environmental Protection Agency (EPA) proposed two new sets of standards in July 2009, which requires ships that have compression-ignition engines with a capacity of 30 liters or more per cylinder in U.S. waters to cut...

Revamp Your Furnace – Enhance Technical & Financial Performance

Mar 23, 2010
Yong Wang
Furnace revamps provide opportunities to enhance new technologies, add feedstock flexibility, increase production capacity, improve efficiency and meet more stringent environmental regulations. With the current economic situation and anticipated environmental requirements, construction of...

Full Potential Conversion of Vacuum Resids

Mar 23, 2010
Irv Wiehe
Present vacuum resid conversion processes, either coking or hydroconversion, are far from achieving their maximum conversion. With the remaining petroleum resources, on average, having a greater fraction of the vacuum resid fraction, it is imperative that new resid conversion processes or schemes...

Catastrophic Failure of a Dissimilar Metal Weld in a High Pressure Steam Venturi

Mar 23, 2010
Carl G. Matherne
In mid-2009 at the BASF FINA Petrochemical L.P. Steam Cracker in Port Arthur, Texas, a venturi-type flow meter in super-high-pressure steam service ruptured catastrophically, resulting in a major release of pressure and trip of the plant. Initially a steam leak was observed at the flow meter, and...

Fuel Performance Parameters for Marine Engines

Mar 23, 2010
The regulations for sulfur reduction in marine fuels are impacting the whole spectrum beginning from the production of the fuel in the refineries to the end use in Marine diesel engines. To start with, from 1/1/2010, the European Union regulations call for use of fuel with a maximum of 0.1% sulfur...

Feedstock Contaminants: A Case Study

Mar 23, 2010
Vasily Simanzhenkov
An advanced characterization program was designed and implemented to identify the chemical nature of contaminants present in the feed to a flexi-cracker. The solid contaminants removed from the naphtha feed had similar amounts of inorganic and organic materials. Iron and silicone were the most...

Integrated Refinery Cracker, the New Paradigm

Mar 23, 2010
Osman Aboul-Nasr
The new trends in crackers are higher capacity and heavier feedstock. This makes the integration between refineries and crackers significantly more beneficial. The importance of integration becomes a more paramount issue. Since several new refineries and cracker / derivatives complexes are...

Options for Mercury Removal in Ethylene Plants

Mar 23, 2010
Jayant Gorawara
Ethylene producers have faced the challenge of feedstock contaminants for decades. However, with current industry transitions and surplus capacity, the low cost producer will have a real advantage in terms of survivability. The ability to leverage opportunities to improve the cost position on...

Ultra Low NOx Burner Performance in an Ethylene Cracking Furnace

Mar 23, 2010
Patrick C. Riley
In recent years, the global tightening of emissions standards has created numerous challenges for the owners and operators of ethylene cracking furnaces. Achieving ultra-low NOx emission levels in ethylene cracking furnaces, where the operating temperatures routinely range between 2000°F to 2200°F...

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