Petrochemicals

Anisole and Guaiacol Deoxygenation Over Pt/Sn On Monolith Catalyst Supports

Oct 17, 2011
Miguel Angel Gonzalez Borja
Upgrading of pyrolysis oil vapors requires a catalytic reactor able to treat high reactant flow rates without generating a large pressure drop. Therefore, monolithic catalysts appear as good candidates for this purpose. In this contribution, low-surface-area Inconel monoliths were coated with in-...

A New Class of Polymer Inhibitors

Mar 16, 2011
P. N. Ramaswamy
Polymer inhibitors are used within an ethylene plant in locations which are susceptible to aggressive polymer formation i.e. Primary Fractionator, Compressors, Pyrolysis Gasoline Strippers and within the Gas Separation units. Over the years, the use of such additives has been extended to newer...

Loss of Downcomer Seal on a Depropanizer During a Plant Start up

Mar 16, 2011
Andre Bernard
The bottom C4’s product specification could not be met on the Depropanizer tower during a plant start up. The olefins unit had been started with a new start up procedure, which involved significant reduction in feed rates to the unit until achieving on spec ethylene. C3 & C4’s product were to...

Improved Ethylene Cracking Furnace Control with Modern Process Mass Spectrometers

Mar 16, 2011
Peter J. Traynor
Whereas process mass spectrometers have been used as an alternative (lower cost) solution to multiple process gas chromatograph installations for many years, their use has been somewhat limited by their complexity - both real and perceived. The latest generation of process mass spectrometers has...

Operational Inputs Into the Mechanical Integrity Program

Mar 15, 2011
F. Russ Davis
A predictive mechanical integrity (MI) program is based on the following: * Damage mechanisms that affect process equipment. * Rate at which degradation progresses. * Ability of the inspection group to identify and correct equipment damage before equipment failure. Operational temperature, pressure...

Practices to Mitigate NOx Risk In Cryogenic Section of Ethylene Plants

Mar 15, 2011
Jennifer L. Bancroft
In May 2010 the Ethylene Producers Committee NOx Safety Sub-Committee sponsored a discussion on practices to mitigate NOx risk in the cryogenic section of ethylene plants. The meeting was attended by representatives of 10 ethylene producers, 4 ethylene contractors and other contractors, 2 additive...

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